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• W2030172673 abstract "Results obtained from electrical impedance spectroscopy at n-GaAs in the dark with Fe(CN)63-, ClO− and BrO− in alkaline solution indicate that the cathodic reduction current is due mainly to electron-hole recombination at the surface. The same conclusion also holds for the recombination of photo-generated holes at illuminated n-GaAs in indifferent electrolyte. Electroluminescence measurements showed that surface recombination with the hypohalites is more effective than with Fe(CN)63-. Quantum efficiency measurements at p-GaAs revealed that the second charge transfer step of the hypohalite reduction can involve either the capture of an electron by or the injection of a hole from a surface intermediate. This result leads to a slight revision of a mechanism previously proposed for the reduction of ClO− and BrO− at GaAs." @default.
• W2030172673 created "2016-06-24" @default.
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• W2030172673 date "1992-07-01" @default.
• W2030172673 modified "2023-10-03" @default.
• W2030172673 title "The reduction of hypohalites at GaAs electrodes: Charge-transfer and recombination processes" @default.
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• W2030172673 doi "https://doi.org/10.1002/bbpc.19920960708" @default.
• W2030172673 hasPublicationYear "1992" @default.
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