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• W2030190720 abstract "Semi-empirical effective charge calculations were made of crystal field effects and the corresponding energy level splittings for NNN-F- compensated centres in a number of RE3+: fluorite structure systems. While the results obtained confirm that such centres were indeed observed in a number of experimental investigations of these dopant: lattice systems, in at least one instance (the B centre in the Er3+:CaF2 system) such identification appears to be untenable. Model reconstructions were also made of local lattice distortions in the centres in the Eu3+:SrF2 and Er3+:SrF2 systems. The two centres are structurally related but the corresponding local distortions appear to be qualitatively different, this result is discussed in the context of other recent work in the field. Finally, the procedure developed was used to improve the phenomenological calculation of Bqk values for the trigonal entre in the Eu3+:BaF2 system, demonstrating its utility in such applications by significantly improving final fit quality." @default.
• W2030190720 created "2016-06-24" @default.
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• W2030190720 date "1992-02-17" @default.
• W2030190720 modified "2023-09-26" @default.
• W2030190720 title "Crystal fields and microscopic local structures of some trigonal symmetry centres in fluorite crystals doped with trivalent rare-earth ions" @default.
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• W2030190720 doi "https://doi.org/10.1088/0953-8984/4/7/012" @default.
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