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- W2030202202 abstract "The structure and properties of molybdenum-doped soda-borate glasses were studied by means of electron paramagnetic resonance as functions of the molybdenum oxide concentration in the range 1–25 mol% MoO3, the keeping time of the samples at the preparation temperature in the range of 15–180 min, the preparation temperature in the range of 900–1300°C, and the soda-borate matrix composition in the range 0–34 mol% Na2O. The EPR measurements gave evidence of the existence of three types of site for the Mo5+ ions, their relative fraction as well as the paramagnetic center density and the EPR lineshape symmetry being dependent on the above-mentioned factors. The evolution of the 11B NMR lineshape in the studied samples also showed that the fourfold-coordinated boron atoms fraction is greatly influenced by the modification of these factors. The good agreement between the structural information obtained by 11B NMR and Mo5+ EPR studies recommends the EPR spectra of Mo5+ ions as an excellent sensor for the structure of the borate glasses." @default.
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- W2030202202 date "1983-08-01" @default.
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- W2030202202 title "Magnetic resonance of the B2O3Na2OMoO3 vitreous system" @default.
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