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- W2030214292 abstract "A palladium-catalyzed intermolecular γ-arylation of γ-branched α,β-unsaturated aldehydes has been developed. The reaction allows congested quaternary centers to be forged on a remote position from the carbonyl group, affording a variety of products in high yield and with consistently high stereoselectivity using very low catalyst loadings. The synthetic utility of the products has been highlighted by a series of derivatizations and the potential of the method to be extended to remote ε-functionalization has been demonstrated." @default.
- W2030214292 created "2016-06-24" @default.
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- W2030214292 date "2013-01-01" @default.
- W2030214292 modified "2023-09-27" @default.
- W2030214292 title "Access to congested quaternary centers by Pd-catalyzed intermolecular γ-arylation of unactivated α,β-unsaturated aldehydes" @default.
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- W2030214292 doi "https://doi.org/10.1039/c3sc50806d" @default.
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