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• W2030275017 abstract "An open capsule-type octanuclear heterometallic sulfide cluster without an intramolecular inversion center [Ru(η6-C6Me6){P(OMe)3}{MoO(μ3-S)3}(CuI)2]2 (5) has been synthesized for the first time by stepwise connection of three mononuclear building blocks, i.e., (i) [RuCl2(η6-C6Me6){P(OMe)3}] (1a) as an octahedral terminal building block to control the direction of cluster expansion, (ii) [MoOS3]2- as a tetrahedral polydentate building block owing to the strong coordination ability of the S atoms, and (iii) a CuI building block to form a trigonal planar (μ-S)2CuI unit or to form a linkage unit of two incomplete cubane-type octanuclear frameworks. The stepwise connection was made in the following order: [RuCl2(η6-C6Me6){P(OMe)3}] (1a, mononuclear) → [Ru(η6-C6Me6){P(OMe)3}{MoOS(μ2-S)2}] (2a, dinuclear) → [Ru(η6-C6Me6){P(OMe)3}{MoO(μ2-S)2(μ3-S)}CuI] (3a, butterfly-type trinuclear) → [Ru(η6-C6Me6){P(OMe)3}{MoO(μ3-S)3}(CuI)2]2 (5). When P(OMe)3 was replaced by P(OEt)3, which is more bulky than P(OMe)3, in the starting ruthenium building block [RuCl2(η6-C6Me6){P(OEt)3}] (1b, mononuclear), only the tetranuclear incomplete single cubane cluster [Ru(η6-C6Me6){P(OEt)3}{MoO(μ3-S)3}(CuI)2] (6) was generated, owing to the steric effect of P(OEt)3." @default.
• W2030275017 created "2016-06-24" @default.
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• W2030275017 date "2005-09-27" @default.
• W2030275017 modified "2023-10-17" @default.
• W2030275017 title "Synthesis and Crystal Structure of an Open Capsule-Type Octanuclear Heterometallic Sulfide Cluster with a Linked Incomplete Double Cubane Framework without an Intramolecular Inversion Center" @default.
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• W2030275017 doi "https://doi.org/10.1021/ja051748q" @default.
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