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• W2030287483 endingPage "743" @default.
• W2030287483 startingPage "727" @default.
• W2030287483 abstract "Abstract The reactions of HS2H+· with the series of reference bases: H2S, CH2O, C3H3F3O (1,1,1-trifluoropropanone), C2H5I, C6H4F2 (o-difluorobenzene), HCO2H, C4H8 (trans-2-butene), c-C3H6, n-C3H6, CH3OH, CH3SH, and C2H5OH, with proton affinities ranging from 168.5–185.6 kcal/mol, have been investigated with a selected ion flow tube (SIFT) to bracket the gas basicity (GB) and proton affinity (PA) of the hydrothiosulfeno radical (HS2·). The recently developed thermokinetic method of Bouchoux et al. [Int. J. Mass Spectrom. Ion Processes 153 (1996) 37] applied to the data gives GB(HS2·) = 169.8 ± 2.2 kcal/mol and PA(HS2·) = 178.0 ± 2.4 kcal/mol, consistent with but more accurate than the simple bracketing procedure. The proton affinity is used to calculate the enthalpy of formation of HS2·, giving ΔHf○298(HS2·) = 25.0 ± 2.5 kcal/mol; this result is compared with the relatively few other reported determinations of this quantity. The HS2· radical is of potential importance to chemical processes in interstellar clouds (ISC), as well as to fuel refinery and atmospheric chemistry. The HS2H+· reactions and a parallel study of the reactions of S2+· are discussed." @default.
• W2030287483 created "2016-06-24" @default.
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• W2030287483 date "1999-04-01" @default.
• W2030287483 modified "2023-10-10" @default.
• W2030287483 title "Gas-phase reactivity of HS2H+· and S2+·: an investigation of the gas basicity and proton affinity of HS2·" @default.
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• W2030287483 doi "https://doi.org/10.1016/s1387-3806(98)14175-1" @default.
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