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- W2030302693 abstract "The benzo-tetracarbahexaborane derivative 1 reacts with pentamethylcyclopentadienylcobalt-bisethene, cyclopentadienylrhodium-bisethene and tricarbonyliron-biscyclooctene to yield the cobalt, rhodium, and iron complexes 5, 6, and 7, in which the metal is bound η4 to the benzo ring. In contrast the reactions of 1 with cyclopentadienylcobalt-bisethene and cyclopentadienyliron-cyclooctadiene form the 1,3-dihydro-1,3-diboranaphthalenecobalt complexes 8, 9 and the iron-iron triple-decker complex 10. The constitutions of the complexes 5–10 are derived from spectroscopic data and are confirmed by X-ray structure analyses for 5, 7, 8 and 10. Das Benzo-tetracarbahexaboran-Derivat 1 reagiert mit Pentamethylcyclopentadienylcobalt-bis(ethen), Cyclopentadienyl-rhodium-bis(ethen) und Tricarbonyleisen-bis(cycloocten) unter Bildung der Cobalt-, Rhodium- und Eisen-Komplexe 5, 6 und 7, in denen das Metall η4 an den Benzoring gebunden ist. Im Gegensatz dazu ergeben die Umsetzungen von 1 mit Cyclopentadienyl-cobalt-bis(ethen) und Cyclopentadienyleisen-cyclooctadien die 1,3-Dihydro-1,3-diboranaphthalincobalt-Komplexe 8, 9 und den Dieisen-Tripeldecker-Komplex 10. Die Konstitutionen der Komplexe 5–10 sind aus den spektroskopischen Daten abgeleitet und durch Kristallstrukturanalysen für 5, 7, 8 und 10 bestätigt." @default.
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- W2030302693 date "1994-11-01" @default.
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- W2030302693 title "Synthese und Strukturen von Benzo-tetracarbahexaboran-und 1,3-Dihydro-1,3-diboranaphthalin-Metallkomplexen" @default.
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- W2030302693 doi "https://doi.org/10.1016/0022-328x(94)85027-5" @default.
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