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- W2030303039 abstract "This paper presents a study of the dissociative recombination of C3H7+ with electrons in a heavy-ion storage ring, CRYRING. Cross sections were measured as a function of kinetic energy and found to be extremely rapid with a dependence of E-1.10±0.01. The recombination cross section was integrated to yield a thermal rate coefficient of 1.9 × 10-6 cm3 s-1. Product branching ratios were measured and proved to be quite complex. Although 16 channels are energetically accessible at 0 eV, it was not possible to assign branching ratios to all channels; some related channels were combined in the analysis. The results show that the dissociation channel corresponding to loss of a single hydrogen atom dominates, with a branching ratio of 0.42. Multiple H-loss channels are also observed. Product channels that involve breaking a C−C bond have a combined branching ratio ranging from 0.34 to 0.39." @default.
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- W2030303039 date "2003-03-11" @default.
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- W2030303039 title "Rates and Products of the Dissociative Recombination of C<sub>3</sub>H<sub>7</sub><sup>+</sup> in Low-Energy Electron Collisions" @default.
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- W2030303039 doi "https://doi.org/10.1021/jp027729+" @default.
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