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- W2030312079 abstract "The electrochemical behaviour of tin in de-aerated sodium perchlorate was studied using potentiodynamic and potentiostatic techniques. Tin behaviour in sodium perchlorate has been complicated unexpectedly by the reduction of the perchlorate anion. It is shown that the reduction process takes place within a potential region comprising the negative side of the double layer region and the positive side of the hydrogen region (−0.7V ≤ E ≤ −1.3V). The presence of oxide on the electrode surface favours the reduction reaction, which may occur in two steps; the formation of basic tin(II) chloride followed by its reduction, producing chloride." @default.
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- W2030312079 date "1997-02-01" @default.
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- W2030312079 title "Electrochemical study of perchlorate reduction at tin electrodes" @default.
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- W2030312079 doi "https://doi.org/10.1016/s0022-0728(96)04894-2" @default.
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