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- W2030333460 abstract "A simple and versatile catalytic system for N-alkylation of sulfonamides with various alcohols based on a catalytic hydrogen transfer reaction has been developed under a low catalyst loading of [Cp*IrCl2]2 (0.050−1.5 mol %) in the presence of t-BuOK. A variety of N-alkylated sulfonamides were prepared in good to excellent yields. Mechanistic investigations revealed that the key catalytic species in the present system is a sulfonylimido-bridged unsaturated diiridium complex [(Cp*Ir)2(μ-NTs)2]." @default.
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- W2030333460 date "2010-02-25" @default.
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- W2030333460 title "Simple and Versatile Catalytic System for N-Alkylation of Sulfonamides with Various Alcohols" @default.
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- W2030333460 doi "https://doi.org/10.1021/ol1002434" @default.
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