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- W2030342844 abstract "Laser flash photolysis was used to investigate the fast reaction of 4-(2-p-dimethylaminophenyl ethynil)-6,6-dimethyl-3-cyano-5,6-dihydro-2(1H)-pyridone (DHP) with the intermediate complex of platinum(III), PtCl2−5, appearing in the photoreduction of PtCl2−6 in methanol. Kinetic and spectroscopic parameters of the new-formed complex PtCl2−5|DHP were determined. DHP in this complex is coordinated by an −N(CH3)2 group nitrogen atom since a similar molecule with this group substituted by −O(CH3) does not react with PtCl2−5. Steady-state photolysis has shown that the transformation Pt(III) å Pt(II) involves escape of DHP from the coordination sphere since the final complex Pt(II)|DHP is not formed." @default.
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- W2030342844 date "1992-01-01" @default.
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- W2030342844 title "Laser pulse photolysis study of the reaction of the intermediate platinum(III) complex PtCl2−5 and 4-(2-p-dimethylaminophenyl ethynil)-6,6-dimethyl-3-cyano-5,6-dihydro-2(1H)-pyridone" @default.
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- W2030342844 doi "https://doi.org/10.1016/1010-6030(92)85147-m" @default.
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