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- W2030351009 abstract "Anionic complexes of the type [M(CO)2(diket)(η3-allyl)Cl]− (where M is Mo or W and diket is a β-diketonate group) are readily prepared by the addition of allyl chloride to [M(CO)4(diket)]− anions. NMR measurements indicate an equilibrium between two conformers due to rotation of the allyl groups. [M(CO)5(OC(=O)R)]− anions also react with allyl chloride to form η3-allyl complex anions. Some structural aspects of both the diketonate and carboxylate derivatives are discussed." @default.
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- W2030351009 date "1977-05-01" @default.
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- W2030351009 title "Carbonyl (η3-allyl) anions of molybdenum and tungsten" @default.
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- W2030351009 doi "https://doi.org/10.1016/s0022-328x(00)91731-5" @default.
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