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- W2030355825 abstract "The bonding in Cr(NO)4 is very ionic, with about 1.5 electrons donated from the Cr to the NO 2π orbitals. There is also a NO σ donation of about 0.5 electrons to the Cr, yielding a net charge on Cr of about 1. A large MCSCF expansion is needed to describe both the ionic and covalent contributions to the Cr 3d–NO 2π bonding. This bonding is compared to that in the isoelectronic Ni(CO)4." @default.
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- W2030355825 date "1986-09-01" @default.
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- W2030355825 title "A comparison of the bonding in Cr(NO)4 and Ni(CO)4" @default.
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- W2030355825 doi "https://doi.org/10.1063/1.451831" @default.
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