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- W2030357832 abstract "Silver colored ribbon-like crystals of K1 −xSn5 −xBi11 + xSe22 (x≈ 0.33) were prepared by direct combination of K2Se, Bi2Se3, Sn and Se at 800 °C. A structure determination was carried out for K0.66Sn4.82Bi11.18Se22. Bi2Te3-type and NaCl-type building units are connected to form a new kind of three-dimensional anionic framework with K+ filled tunnels. The building units are assembled from distorted, edge-sharing (Bi,Sn)Se6 octahedra. Bi and Sn atoms are disordered over all metal sites of the chalcogenide network while the K site is only one third occupied. The charge transport measurements of K0.66Sn4.82Bi11.18Se22 at room temperature reveal an electrical conductivity of 450 S cm−1 and a thermopower of −43 µV K−1. The thermal conductivity is 1.5 W m−1 K−1. An optical band gap of approximately 0.12 eV was determined at room temperature. K0.66Sn4.82Bi11.18Se22 melts congruently at 680 °C." @default.
- W2030357832 created "2016-06-24" @default.
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- W2030357832 date "2000-01-01" @default.
- W2030357832 modified "2023-09-23" @default.
- W2030357832 title "Structure and thermoelectric properties of the new quaternary tin selenide K1 − xSn5 − xBi11 + xSe22" @default.
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- W2030357832 doi "https://doi.org/10.1039/b000045k" @default.
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