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- W2030379726 abstract "Reactions of Rh(ClO4)(CO)(PPh3)2 with nitriles produce new cationic rhodium(I) complexes, [RhL(CO)(PPh3)2]ClO4 [L = CH3CN (1), CH3CH2CH2CN (2) or C6H5CN (3)], whose spectral data suggest that the nitriles are coordinated through the nitrogen atom. Formation constants for the reaction Rh(ClO4)(CO)(PPh3)2 + L ⇋ [RhL(CO)(PPh3)2]ClO4, have been measured to be 1.01 × 105 M−1 (CH3CN), 1.07 × 105 M−1 (CH3CH2CH2CN) and 2.59 × 104 M−1 (C6H5CN) at 25°C in monochlorobenzene. The differences in the formation constants for the different nitriles seem to be predominantly due to differences in ΔH (not to differences in ΔS). The nitriles in 1–3 are readily replaced with nitrogen base ligands (unsaturated nitriles and pyridine) and PPh3." @default.
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- W2030379726 date "1986-01-01" @default.
- W2030379726 modified "2023-09-27" @default.
- W2030379726 title "Synthesis, formation constants and reactions of cationic rhodium(I) complexes of nitriles" @default.
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- W2030379726 doi "https://doi.org/10.1016/s0277-5387(00)83511-1" @default.
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