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- W2030392903 abstract "The synthesis of the 4-chloro-, 4-iodo- and 4-fluoro derivatives of 6-phenyl-[1(3)-15N]pyrimidine is described. The amination of 4-chloro- and 4-fluoro–6-phenyl-[1(3)-15N]pyrimidine with potassium amide in liquid ammonia at −75° occurs to a great extent (93% ± 5% and 73% ± 5%, respectively) according to the ANRORC-mechanism. In the conversion of 4-iodo-6-phenyl-pyrimidine into the corresponding 4-amino compound the ANRORC-mechanism occurs to the extent of about 10% only; evidence has been put forward that in this conversion an EA-mechanism is mainly operative." @default.
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- W2030392903 date "2010-09-02" @default.
- W2030392903 modified "2023-09-28" @default.
- W2030392903 title "On the mechanism of the amination of 4-halogeno-6-phenylpyrimidines with potassium amide in liquid ammonia" @default.
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- W2030392903 doi "https://doi.org/10.1002/recl.19720911204" @default.
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