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- W2030398212 abstract "The reactions of methylglyoxal in aqueous solutions of Tris [tris(hydroxymethyl)aminomethane] buffer were examined at 600 MHz by two-dimensional NMR experiments selected to circumvent the difficulties associated with spectral assignment in the presence of intense resonances due to both solvent and buffer. Methylglyoxal, generated in situ from glyceraldehyde 3-phosphate, reacted with Tris to yield principally a mixture of 3,6-dioxa-8-azabicyclo[3.2.1]octanes. 1H and 13C NMR parameters are reported for three compounds containing this little-known ring system and structural influences compared with those in related compounds. A much slower reaction led to the ultimate formation of N-[tris(hydroxymethyl)methyl]alanine. Implications for various enzyme assays are considered and the results are compared with previous observations of reactions of α-dicarbonyl compounds with α-amino alcohols. © 1997 by John Wiley & Sons, Ltd." @default.
- W2030398212 created "2016-06-24" @default.
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- W2030398212 date "1997-03-01" @default.
- W2030398212 modified "2023-09-23" @default.
- W2030398212 title "NMR Characterization of3,6-Dioxa-8-azabicyclo[3.2.1]octanes andN-[Tris(hydroxymethyl)methyl]alanine Formedfrom Methylglyoxal in Tris Buffer Solutions" @default.
- W2030398212 doi "https://doi.org/10.1002/(sici)1097-458x(199703)35:3<191::aid-omr54>3.0.co;2-c" @default.
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