FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2030431315> ?p ?o ?g. }

• W2030431315 endingPage "793" @default.
• W2030431315 startingPage "779" @default.
• W2030431315 abstract "Abstract Toluenes underwent base‐promoted selective benzylic carbon‐hydrogen bond activation (CHA) with rhodium porphyrin chlorides (Rh(por)Cl). In the absence of nucleophilic base, both aryl and benzylic rhodium porphyrins were formed. In the presence of nucleophilic base, the selectivity, rates and functional group compatibilities of benzylic activation reactions were enhanced. K 2 CO 3 was found to be the optimal base to achieve the best yields. Ortho‐, meta‐ and para‐substituted toluenes in the presence of K 2 CO 3 yielded the corresponding rhodium porphyrin benzyls in high yields both in solvent‐free conditions and in benzene solvent. Mechanistically, in the absence of nucleophilic base, a cationic rhodium(III) porphyrin species together with some rhodium(II) porphyrin are the most likely intermediates to account both the aryl and benzylic CHA. In the presence of a base, Rh(por)OH is generated by ligand substitution with Rh(por)Cl and rapidly undergoes reduction to give rhodium(II) porphyin dimer and H 2 O 2 . The key rhodium porphyrin intermediates for benzylic CHA were found to be rhodium(II) porphyrin dimer and hydrides as observed by 1 H NMR spectroscopy, which underwent parallel benzylic CHA reactions with the rhodium(II) porphyrin dimer being the more reactive intermediate." @default.
• W2030431315 created "2016-06-24" @default.
• W2030431315 creator A5045726209 @default.
• W2030431315 creator A5050869407 @default.
• W2030431315 creator A5055068205 @default.
• W2030431315 creator A5080221429 @default.
• W2030431315 date "2013-04-02" @default.
• W2030431315 modified "2023-10-16" @default.
• W2030431315 title "Base‐Promoted Selective Activation of Benzylic Carbon‐Hydrogen Bonds of Toluenes with Rhodium(III) Porphyrin Chloride: Synthetic Scopes and Mechanism" @default.
• W2030431315 cites W136347255 @default.
• W2030431315 cites W1970994010 @default.
• W2030431315 cites W1971999359 @default.
• W2030431315 cites W1973573267 @default.
• W2030431315 cites W1974727789 @default.
• W2030431315 cites W1979973516 @default.
• W2030431315 cites W1999589112 @default.
• W2030431315 cites W2001956039 @default.
• W2030431315 cites W2009314028 @default.
• W2030431315 cites W2009539837 @default.
• W2030431315 cites W2010584571 @default.
• W2030431315 cites W2012780101 @default.
• W2030431315 cites W2025581350 @default.
• W2030431315 cites W2026721826 @default.
• W2030431315 cites W2035209807 @default.
• W2030431315 cites W2036217565 @default.
• W2030431315 cites W2036460050 @default.
• W2030431315 cites W2037682587 @default.
• W2030431315 cites W2045487908 @default.
• W2030431315 cites W2049700364 @default.
• W2030431315 cites W2052907048 @default.
• W2030431315 cites W2059820218 @default.
• W2030431315 cites W2060581549 @default.
• W2030431315 cites W2067456389 @default.
• W2030431315 cites W2069676491 @default.
• W2030431315 cites W2074996309 @default.
• W2030431315 cites W2080339357 @default.
• W2030431315 cites W2083178838 @default.
• W2030431315 cites W2180105697 @default.
• W2030431315 cites W2316210352 @default.
• W2030431315 cites W4230924963 @default.
• W2030431315 doi "https://doi.org/10.1002/jccs.201200635" @default.
• W2030431315 hasPublicationYear "2013" @default.
• W2030431315 type Work @default.
• W2030431315 sameAs 2030431315 @default.
• W2030431315 citedByCount "7" @default.
• W2030431315 countsByYear W20304313152014 @default.
• W2030431315 countsByYear W20304313152015 @default.
• W2030431315 countsByYear W20304313152018 @default.
• W2030431315 countsByYear W20304313152022 @default.
• W2030431315 crossrefType "journal-article" @default.
• W2030431315 hasAuthorship W2030431315A5045726209 @default.
• W2030431315 hasAuthorship W2030431315A5050869407 @default.
• W2030431315 hasAuthorship W2030431315A5055068205 @default.
• W2030431315 hasAuthorship W2030431315A5080221429 @default.
• W2030431315 hasConcept C155647269 @default.
• W2030431315 hasConcept C161790260 @default.
• W2030431315 hasConcept C178790620 @default.
• W2030431315 hasConcept C178907741 @default.
• W2030431315 hasConcept C183882617 @default.
• W2030431315 hasConcept C185592680 @default.
• W2030431315 hasConcept C188027245 @default.
• W2030431315 hasConcept C2779480358 @default.
• W2030431315 hasConcept C2779546866 @default.
• W2030431315 hasConcept C2780263894 @default.
• W2030431315 hasConcept C2781076698 @default.
• W2030431315 hasConcept C521398313 @default.
• W2030431315 hasConcept C75473681 @default.
• W2030431315 hasConceptScore W2030431315C155647269 @default.
• W2030431315 hasConceptScore W2030431315C161790260 @default.
• W2030431315 hasConceptScore W2030431315C178790620 @default.
• W2030431315 hasConceptScore W2030431315C178907741 @default.
• W2030431315 hasConceptScore W2030431315C183882617 @default.
• W2030431315 hasConceptScore W2030431315C185592680 @default.
• W2030431315 hasConceptScore W2030431315C188027245 @default.
• W2030431315 hasConceptScore W2030431315C2779480358 @default.
• W2030431315 hasConceptScore W2030431315C2779546866 @default.
• W2030431315 hasConceptScore W2030431315C2780263894 @default.
• W2030431315 hasConceptScore W2030431315C2781076698 @default.
• W2030431315 hasConceptScore W2030431315C521398313 @default.
• W2030431315 hasConceptScore W2030431315C75473681 @default.
• W2030431315 hasIssue "7" @default.
• W2030431315 hasLocation W20304313151 @default.
• W2030431315 hasOpenAccess W2030431315 @default.
• W2030431315 hasPrimaryLocation W20304313151 @default.
• W2030431315 hasRelatedWork W1969618541 @default.
• W2030431315 hasRelatedWork W1976882456 @default.
• W2030431315 hasRelatedWork W2000067460 @default.
• W2030431315 hasRelatedWork W2015235320 @default.
• W2030431315 hasRelatedWork W2039219023 @default.
• W2030431315 hasRelatedWork W2324898221 @default.
• W2030431315 hasRelatedWork W2923272966 @default.
• W2030431315 hasRelatedWork W2952271444 @default.
• W2030431315 hasRelatedWork W2952727089 @default.
• W2030431315 hasRelatedWork W3004624451 @default.
• W2030431315 hasVolume "60" @default.
• W2030431315 isParatext "false" @default.
• W2030431315 isRetracted "false" @default.
• W2030431315 magId "2030431315" @default.

• next