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- W2030433043 abstract "Two novel complexes of Zn(II) chromate with 2,2′-bipyridine have been synthesised: [Zn(bpy)3]CrO4·7.5H2O (1) and catena-(μ-CrO4-O,O′)[Zn(bpy)(H2O)2]·2H2O (2). Complex 1 has been characterised by a structural method. The [Zn(bpy)3]CrO4·7.5H2O crystals have a monoclinic symmetry with space group C2/c and eight chemical units. The chromate ion is not coordinated to the zinc(II) ion. The O(3) and O(4) atoms of CrO42− and O(8) of the water molecule statistically occupy their position with k=0.5, which means that the chromate ions execute reorientational motion between two equilibrium arrangements with equal probability. 4 K electronic spectra (1) revealed the vibrational fine structure in ν3(F2)=820 cm−1 for the spin-forbidden 1A1→3T1 transition. The pure electronic 0–0 transition in 1A1→1T1 was found at 20 270 cm−1. In complex 2 the broad low intensity band at ca. 16 800 cm−1 has been assigned to a forbidden ZnOCr transition in the bridge." @default.
- W2030433043 created "2016-06-24" @default.
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- W2030433043 date "2001-06-01" @default.
- W2030433043 modified "2023-09-27" @default.
- W2030433043 title "Spectroscopic and structural studies of chromate ions in zinc complexes with 2,2′-bipyridine. Analysis of the lowest triplet states in the CrO42− entity" @default.
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- W2030433043 doi "https://doi.org/10.1016/s0277-5387(01)00806-3" @default.
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