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- W2030449341 abstract "Crystal structure and magnetic properties of ternary compounds based on R2Fe14Si2 (off-stoichiometric R2Fe17 type) were investigated. Results of the powder x-ray-diffraction indicated that the compounds examined in this study crystallize in the rhombohedral Th2Zn17-type structure when R is Nd or Gd and in the hexagonal Th2Ni17-type when R is Y, Dy, Ho, or Er. The Curie temperature TC and room-temperature saturation magnetization Ms of R2Fe14Si2 system range from 465 to 572 K and 65 to 150 emu/g, respectively. The behavior of TC is found to follow the root of the de Gennes function and can therefore be ascribed to the strength of the rare-earth–iron exchange interaction. The average magnetic moment of Fe in R2Fe14Si2 is estimated to be approximately 2.0 μB at 77 K. Addition of Si in the binary R-Fe lattice induced a large uniaxial magnetic anisotropy at room temperature in some alloys. Results of M vs T for Er2Fe14Si2 indicate a spin reorientation transition at about 100 and 35 K. Dy2Fe14Si2 and Ho2Fe14Si2 exhibit a remarkable magnetic hardening at low temperatures." @default.
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- W2030449341 date "1993-05-15" @default.
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- W2030449341 title "Crystal structure and magnetic characteristics of alloys based on<i>R</i>‐Fe‐Si (<i>R</i>=Y, Nd, Gd, Dy, Ho, Er)" @default.
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- W2030449341 doi "https://doi.org/10.1063/1.352667" @default.
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