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- W2030459715 abstract "Gas-phase equilibria for clustering reactions of CH3+ with N2 were measured with a pulsed electron-beam high-pressure mass spectrometer. The bond energies were found to show irregular decreases for H3C+(N2)n with n=1, 4, and 6. Due to the formation of the covalent bond with n=1, the positive charge is dispersed in the H3CN2+ complex which is solvated preferentially by three more N2 ligands. The ab initio calculations revealed that the cluster ion with n=4 has the three-fold shell structure, H3CN2+(N2)3, with the C3v symmetry. The most stable cluster ion with n=6 has the four-fold shell structure (N2)1H3CN2+(N2)4. The attachment of n=7 and 8 N2 ligands results in the relaxation of the four-fold structure of the cluster with n=6 to the three-fold one with n=8, (N2)1H3CN2+(N2)3(N2)3, due to the steric congestion." @default.
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- W2030459715 date "2003-07-01" @default.
- W2030459715 modified "2023-09-27" @default.
- W2030459715 title "Thermochemical stabilities of the gas-phase cluster ions H3C+(N2)n" @default.
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- W2030459715 doi "https://doi.org/10.1016/s1387-3806(03)00097-6" @default.
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