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- W2030459816 abstract "The chromatographic behaviour of some naturally occurring ergot alkaloids of the peptide type (“ergopeptines”) and their isomers was examined by reversed-phase high-performance liquid chromatography. A satisfactory separation of eight natural ergot alkaloids and their isomers on LiChrosorb RP-18 is achieved with a neutral mobile phase of acetonitrile—water at pH 7 without addition of alkaline modifiers such as triethylamine or carbonate. For a better correlation of retention data with chemical structure, retention indices have been calculated using the homologous series of 2-ketoalkanes as reference compounds. On the octadecylsilica columns, the differences in retention indices (ΔI values) were nearly constant for particular compounds or molecular fragments, even when the absolute I values differed by 100 units or more." @default.
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- W2030459816 date "1985-01-01" @default.
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- W2030459816 title "Retention indices of some ergopeptines in reversed-phase high-performance liquid chromatography" @default.
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- W2030459816 doi "https://doi.org/10.1016/0021-9673(85)80030-3" @default.
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