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- W2030483075 endingPage "4158" @default.
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- W2030483075 abstract "The aggregation of methylene blue around different polyelectrolytes is studied by diafiltration, UV-vis, and (1)H NMR spectroscopies. Poly(sodium acrylate-co-sodium maleate) induces the formation of higher-order aggregates, showing a typical polyelectrolyte behavior dominated by long-range electrostatic interactions with the dye which are highly dependent on the ionic strength. Poly(sodium 4-styrenesulfonate) presents a high dispersant ability of methylene blue, showing what we can call a typical polyaromatic-anion behavior characterized by the presence of short-range aromatic-aromatic interactions with the dye which are less dependent on the ionic strength. An intermediate behavior is found for the copolymers poly(sodium 4-styrenesulfonate-co-sodium maleate) at two different comonomer compositions, related to a different probability of the polymers to form and stabilize ion pairs in hydrophobic environments. Their behavior is a function of the linear aromatic density, which is related to the comonomeric structure." @default.
- W2030483075 created "2016-06-24" @default.
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- W2030483075 date "2010-03-04" @default.
- W2030483075 modified "2023-10-14" @default.
- W2030483075 title "Influence of the Linear Aromatic Density on Methylene Blue Aggregation around Polyanions Containing Sulfonate Groups" @default.
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- W2030483075 doi "https://doi.org/10.1021/jp909105r" @default.
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