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- W2030485865 abstract "Iron complexes with the Schiff bases of quinolinecarbaldehyde and pyridinecarbaldehyde were prepared. Mössbauer spectra and magnetic susceptibilities of the compounds, Fe(pipa)2(NCS)2, Fe(pa)2(NCS)2, Fe(pot)2(NCS)2·1/2CHCl3, Fe(ppt)2(NCS)2, Fe(ppca)2(NCS)2, and Fe(ppa)2(NCS)2 were studied in the temperature range between 298 and 27 K. It was found that these complexes showed an incomplete 5T2-1A1 transition in the solid. The compound Fe(poca)2(NCS)2 also showed a similar phenomenon. The observations of the behavior of the various complexes indicated that the magnetic changeover from spin-paired to spin-free would be closely associated with a modification of the crystal lattice. The FeL′Cl2(L′: the Schiff bases of quinolinecarbaldehyde) were found to have distorted tetrahedral structures." @default.
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- W2030485865 date "1976-09-01" @default.
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- W2030485865 title "Studies of Iron(II) Complexes with Several Schiff Bases: New Examples of<sup>5</sup>T<sub>2</sub>-<sup>1</sup>A<sub>1</sub>Equilibrium" @default.
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- W2030485865 doi "https://doi.org/10.1246/bcsj.49.2427" @default.
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