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- W2030487078 endingPage "3556" @default.
- W2030487078 startingPage "3550" @default.
- W2030487078 abstract "We follow up a previous suggestion that x-ray photoelectron spectroscopy line shapes can be used to estimate the degree of screening orbital delocalization. Using compounds $R{mathrm{Pd}}_{3}$ ($R$ = La, Ce, Pr, Nd, and Sm) we show that there can be appreciable but decreasing mixing of the $4f$ states with the extended conduction-band states in the series of $R{mathrm{Pd}}_{3}$ compounds in going from La to Nd. This mixing is, however, not detectable by photoemission in Sm${mathrm{Pd}}_{3}$. We discuss this mixing in both initial and final states. We conclude that the major initial-state mixing involves ${f}^{0}ensuremath{-}{f}^{1}$ configurations in Ce${mathrm{Pd}}_{3}$. The major mixing in the final states always involves the ${f}^{n}$ and ${f}^{n+1}$ configurations, where the ${f}^{n+1}$ configuration has a negligible effect for Sm and heavier elements. The implication of this is that core-level spectroscopies can give reliable information on the $f$ count in compounds of samarium and the heavier rare-earth metals." @default.
- W2030487078 created "2016-06-24" @default.
- W2030487078 creator A5053630523 @default.
- W2030487078 creator A5031784922 @default.
- W2030487078 date "1982-03-15" @default.
- W2030487078 modified "2023-09-27" @default.
- W2030487078 title "Invalidity of4fcount determination and possibilities for determination of4fhybridization in intermetallics of the light rare earths by core-level spectroscopy" @default.
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- W2030487078 doi "https://doi.org/10.1103/physrevb.25.3550" @default.
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