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• W2030528040 abstract "[p-But-calix[4]-(O)4-MoIV], generated in situ from [MoCl4·THF2] and the alkali salts of p-But-calix[4]arene, displays the reactivity expected for a d2-carbenoid metal. The reaction carried out in the presence of azobenzene led to the cleavage of the NN bond and the formation of a dimeric MoVI-phenylimido derivative, [{μ-p-But-calix[4]-(O)4}2{MoVI⋮NPh}2], while the reaction with acetylenes led to 2-metallacyclopropene complexes [{p-But-calix[4]-(O)4-Mo}(η2-C2R2)], which converted to 1-metallacyclopropenes, the precursor of alkylidene and alkylidyne functionalities, in the reaction with a hydride source." @default.
• W2030528040 created "2016-06-24" @default.
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• W2030528040 date "2001-05-10" @default.
• W2030528040 modified "2023-09-27" @default.
• W2030528040 title "Molybdenum(IV)-d2 Reactivity in a Quasiplanar Oxo-Environment Modeled by Calix[4]arene: The Reductive Cleavage of NN Double Bond and the Formation of 1-Metallacyclopropene from the Corresponding Alkyne Complexes" @default.
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• W2030528040 doi "https://doi.org/10.1021/om010156n" @default.
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