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- W2030534604 abstract "Immersion precipitated membranes with enhanced fouling resistance are prepared from blends of poly(vinylidene fluoride) (PVDF) and a free-radically synthesized amphiphilic comb polymer having a methacrylate backbone and poly(ethylene oxide) side chains. X-ray photoelectron spectroscopy analysis indicates substantial surface segregation of the comb polymer during membrane coagulation, providing an integrated near-surface coverage of up to 50 vol.% comb for a membrane containing 10 wt.% (14.6 vol.%). The surface coverage increases with comb molecular weight, providing hydrophilic surfaces with excellent stability and substantiating a proposed mechanism for surface localization. Separation surface porosities for comb-modified membranes are up to an order of magnitude higher than PVDF controls. With the combined benefits of fouling resistance and increased porosity, a membrane containing 10 wt.% comb is over 20 times as permeable as a PVDF-only membrane with equivalent separation characteristics after 3 h of filtration of a foulant protein solution." @default.
- W2030534604 created "2016-06-24" @default.
- W2030534604 creator A5051069092 @default.
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- W2030534604 date "2002-06-15" @default.
- W2030534604 modified "2023-10-17" @default.
- W2030534604 title "Design and performance of foul-resistant poly(vinylidene fluoride) membranes prepared in a single-step by surface segregation" @default.
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- W2030534604 doi "https://doi.org/10.1016/s0376-7388(01)00735-9" @default.
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