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• W2030541392 abstract "An efficient method for the reconstruction of the 9-dihydroerythromycin A macrolactone skeleton has been established. The key steps are oxidative cleavage at the 11,12-position and reconstruction after insertion of an appropriate functionalized amino alcohol. Novel 15-membered macrolides, we named as 11a-azalides, were synthesized based on the above methodology and evaluated for their antibacterial activity. Among them, (13R)-benzyloxymethyl-11a-azalide showed the most potent Streptococcus pneumoniae activity, with improved activity against a representative erythromycin-resistant strain compared to clarithromycin (CAM)." @default.
• W2030541392 created "2016-06-24" @default.
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• W2030541392 date "2010-12-30" @default.
• W2030541392 modified "2023-10-13" @default.
• W2030541392 title "Synthesis and Antibacterial Activity of a Novel Class of 15-Membered Macrolide Antibiotics, “11a-Azalides”" @default.
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• W2030541392 doi "https://doi.org/10.1021/ml100252s" @default.
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