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• W2030544754 startingPage "4658" @default.
• W2030544754 abstract "The reaction system Mn/Sn/S/hydrazine/water at ∼150 °C afforded [Mn2SnS4(N2H4)2] (1). The compound has a unique neutral three-dimensional framework with bridging hydrazine ligands and a variety of interconnectivity modes between MnL6 (L = N, S) octahedra. The complex structure of 1 leads to strong antiferromagnetic interactions between the Mn2+ centers and ordering at ∼41 K. The stabilization of 1 underscores the high potential of hydrazine to promote the formation of novel chalcogenide materials under solvothermal conditions." @default.
• W2030544754 created "2016-06-24" @default.
• W2030544754 creator A5013043945 @default.
• W2030544754 creator A5035758112 @default.
• W2030544754 date "2009-04-23" @default.
• W2030544754 modified "2023-10-07" @default.
• W2030544754 title "Use of Hydrazine in the Hydrothermal Synthesis of Chalcogenides: the Neutral Framework Material [Mn₂SnS₄(N₂H₄)₂]" @default.
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• W2030544754 doi "https://doi.org/10.1021/ic900517u" @default.
• W2030544754 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19388637" @default.
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