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• W2030565362 abstract "Mo-substituted cobalt ferrite nanoparticles; CoFe2−2xMoxO4 (0.0≤x≤0.3) were prepared by a one-step solution combustion synthesis technique. The reactants were metal nitrates and glycine as a fuel. The samples were characterized using an X-ray diffraction (XRD), a transmission electron microscope (TEM) and a vibrating sample magnetometer (VSM). XRD analysis revealed a pure single phase of cubic spinel ferrites for all samples with x up to 0.3. The lattice parameter decreases with Mo6+ substitution linearly up to x=0.15, then nonlinearly for x≥0.2. Rietveld analysis and saturation magnetization (Ms) revealed that Mo6+ replaced Fe3+ in the tetrahedral A-sites up to x=0.15, then it replaced Fe3+ in both A-sites and B-sites for x≥0.2. The saturation magnetization (Ms) increases with increasing Mo6+ substitution up to x=0.15 then decreases. The crystallite size decreased while the microstrain increased with increasing Mo6+ substitution. Inserting Mo6+ produces large residents of defects and cation vacancies." @default.
• W2030565362 created "2016-06-24" @default.
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• W2030565362 creator A5019489985 @default.
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• W2030565362 date "2014-11-01" @default.
• W2030565362 modified "2023-09-26" @default.
• W2030565362 title "Structural and magnetic properties correlated with cation distribution of Mo-substituted cobalt ferrite nanoparticles" @default.
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• W2030565362 doi "https://doi.org/10.1016/j.jmmm.2014.05.036" @default.
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