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- W2030583062 abstract "Abstract The complexation behavior of the distally substituted phosphonic acid and phosphonic ester 4- tert -butylcalix[4]arenes (hosts) with 1-chloro-4-(trifluoromethyl)benzene (guest) was examined in chloroform. The complex stability constants ( K s ) and the thermodynamic parameters of the complexation were determined by a spectrofluorometric method using Job's method and van't Hoff theory, respectively. A strong dependence of the host–guest interaction on the extent of distortion in the conformation of calixarene host cavity was obtained. The ‘pinched cone’ conformer of 1,3-substituted calix[4]arenes seems to form a complex with electron-deficient neutral aromatics predominantly through π–π type interaction." @default.
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- W2030583062 date "2002-06-01" @default.
- W2030583062 modified "2023-10-17" @default.
- W2030583062 title "Complex formation between 1-chloro-4-(trifluoromethyl)benzene (guest) and 4-tert-butylcalix[4]arenes (host) distally substituted with phosphonic acid or phosphonic ester groups at the lower rim" @default.
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- W2030583062 doi "https://doi.org/10.1016/s0040-4020(02)00474-x" @default.
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