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- W2030595532 abstract "Methoxo-bridged diiridium complexes of the type [{Ir(μ-OMe)(diolefin)}2] (diolefin = 1,5-cyclooctadiene, tetrafluorobenzobarrelene), in the presence on P- or N-donor ligands, are active catalyst precursors in the catalytic hydrogen transfer of iPrOH to acetophenone. Both the nature of the diolefin and that of additional P- and N-donor ligands have a marked effect in the catalytic outcome of the reactions. DFT theoretical studies have been carried out on the binary catalytic systems composed of the iridium complexes and mono phosphanes (Ir/P = 1/1), which indicated that the operative mechanism in these transformations follows the classic “hydrido” route." @default.
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- W2030595532 date "1979-09-01" @default.
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- W2030595532 title "Iridium complexes with 2,2′-bipyridine and 1,10-phenanthroline: very-active catalysis in hydrogen transfer reactions" @default.
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- W2030595532 doi "https://doi.org/10.1016/0304-5102(79)85005-1" @default.
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