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- W2030604879 abstract "The reaction of Os3(CO)10(NCMe)2 with 2-vinyltetrahydrothiophene (VTHT) at 25°C yielded two products: Os3(CO)10[μ-SCH2CH2C(H)C(H)C(H)CH2](μ-H), 1 (38% yield) and Os2(CO)6[μ-η4-S(CH2)3CHCHCH2](μ-H), 2 (27% yield) after 48 h. Both products were characterized by single-crystal X-ray diffraction analysis. Compound 1 contains a triangular triosmium cluster with ten linear terminal carbonyl ligands, a hydride ligand and a hexadienethiolate ligand. Compound 2 contains only two mutually bonded osmium atoms, six linear terminal carbonyl ligands and a hexenylthiolate ligand that bridges the two osmium atoms via a bridging sulfur atom and three of the carbon atoms at the C-terminus of the hexenyl group. Ring opening of VTHT by a triosmium cluster occurs exclusively at the vinyl-substituted carbon atom." @default.
- W2030604879 created "2016-06-24" @default.
- W2030604879 creator A5008683148 @default.
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- W2030604879 date "1999-07-01" @default.
- W2030604879 modified "2023-10-14" @default.
- W2030604879 title "The effect of a vinyl substituent on the ring opening of a substituted tetrahydrothiophene at a triosmium center" @default.
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- W2030604879 doi "https://doi.org/10.1016/s0022-328x(99)00143-6" @default.
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