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- W2030607084 abstract "Abstract An X-band EPR study of a single crystal of Mn2+ -doped Sr(CH3COO)2 · 1 2 H2O has been carried out at 4.2, 77 and 295 K. The angular variation of EPR spectra with respect to the orientation of the Zeeman field (B) supports the view that the crystal symmetry of Sr(CH3COO)2 · 1 2H 2 O is triclinic, in disagreement with the monoclinic crystal symmetry predicted by some preliminary X-ray studies. As the temperature is lowered, the overall splitting of the EPR spectrum for B along the magnetic X axis of Mn2+ increases relative to that for B along the magnetic Z axis. Finally, at liquid-helium temperature the overall splitting for B along the room-temperature magnetic X axis becomes larger than that for B along the room-temperature magnetic Z axis, implying the interchange of the magnetic Z and X axes below 77 K. The spin-Hamiltonian parameters for Mn2+ in Sr(CH3COO)2 · 1 2 H2O have been determined at the three temperatures of measurement." @default.
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- W2030607084 title "EPR study of a single crystal of Mn2+ -doped Sr(CH3COO)2 · H2O at 295, 77 and 4.2 K" @default.
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- W2030607084 doi "https://doi.org/10.1016/0921-4526(91)90021-6" @default.
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