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• W2030607209 abstract "In the present work, cobalt-doped magnetites, prepared by the co-precipitation method, were mainly studied by X-ray absorption and Mössbauer spectroscopies. From the chemical analysis, it was observed that the continuous increase of Co2+ is followed by a simultaneous decrease of the Fe2+ contents, in the spinel structure. Room temperature Mössbauer parameters indicate that samples are formed by single crystallographic phases of pure magnetite or its Co-substituted analogs. Basing on the inversion of intensities of the Mössbauer lines 1 (leftmost, in the negative Doppler velocity scale) and 2, it is assumed that the Co-substitution occurs essentially, if not only, at octahedral sites of the spinel structure. XAS results obtained at Co K-edge confirm that the Co-substitution occurs preferentially at octahedral coordination sites." @default.
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• W2030607209 date "2004-07-01" @default.
• W2030607209 modified "2023-10-10" @default.
• W2030607209 title "Cation occupancy sites in synthetic Co-doped magnetites as determined with X-ray absorption (XAS) and Mössbauer spectroscopies" @default.
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• W2030607209 doi "https://doi.org/10.1016/j.jmmm.2003.12.1313" @default.
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