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- W2030621855 abstract "EPR studies of single crystal copper tetramethyl ammonium bromide, T2CuBr4[T=(CH3)4N] in the temperature range 77–300 K indicate the largest covalency in this compound compared to similar halogenated pseudotetrahedral copper compounds. The angle cos−1γ between the c axis and the ionic g∥ axis is 12° and 65° at 250 and 220 K, respectively. The change is continuous down to 200 K. The g shift between 300 and 200 K indicates an increase in the strength of the ligand field with lowering of temperature. The magnetic susceptibility ellipsoid and the g-tensor ellipsoid do not coincide in this material. Optical spectra in T2(Cu:Zn)Br4 have been assigned. The nonobservation of an EPR signal in T2(Cu:Zn)Br4 and Cs2CuBr4 indicates that ligand field properties in these pseudotetrahedral compounds are quite different from that of T2CuBr4." @default.
- W2030621855 created "2016-06-24" @default.
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- W2030621855 date "1983-07-15" @default.
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- W2030621855 title "EPR and optical studies in pseudotetrahedral tetramethyl ammonium copper (II) bromide" @default.
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- W2030621855 doi "https://doi.org/10.1063/1.445854" @default.
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