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• W2030622966 abstract "Fluorine Learns to Share Though halides typically coordinate to just one carbon center, their transient coordination to a second carbon (forming a positively charged bridge) explains the spatial dynamics of many reactions. However, unlike chlorine, bromine, and iodine—which can all form such halonium ions—fluorine does not appear to engage in carbon-bridging behavior, presumably because of its very high electronegativity. Struble et al. (p. 57 , see the Perspective by Hennecke ) synthesized a rigid molecule, particularly well-poised to manifest fluoride bridging, and provide evidence for a fluoronium intermediate in a displacement reaction." @default.
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• W2030622966 date "2013-04-05" @default.
• W2030622966 modified "2023-10-18" @default.
• W2030622966 title "Evidence for a Symmetrical Fluoronium Ion in Solution" @default.
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• W2030622966 doi "https://doi.org/10.1126/science.1231247" @default.
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