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- W2030646502 abstract "A new and unexpected interchange reaction has been discovered during an attempt to make fulvalene-linked heterobimetallic complexes by palladium-catalyzed coupling between η 5 -(iodo)cyclopentadienyl and η 5 (trimethyltin)cyclopentadienyl metal complexes. In the presence of Pd the (η 5 -iodocyclopentadienyl)metallo methyl derivatives of general formula (η 5 -IC 5 H 4 )M(CO) n CH 3 (M = Fe, n = 2; M = W, n = 3; M = Mo, n = 3) undergo methyl-iodine exchange, to give the corresponding (η 5 -CH 3 C 5 H 4 )M(CO) n I complexes. The palladium(0) catalysis of the reaction apparently involves an intramolecular transmetallation." @default.
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- W2030646502 date "1991-05-01" @default.
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- W2030646502 title "Methyliodine exchange in (η5-iodocyclopentadienyl)metallo methyl derivatives of iron(II), tungsten(II), and molybdenum(II) in the presence of palladium" @default.
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- W2030646502 doi "https://doi.org/10.1016/0022-328x(91)86390-c" @default.
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