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- W2030664345 abstract "R5Si2Br, R5Si2J und R7Si3Br (R = CH3) sind durch Einwirkung äquivalenter Mengen Brom oder Jod auf R8Si3 bzw. R10Si4 in hoher Ausbeute erhältlich, da die neu eintretenden negativen Substituenten die Si–Bindung gegen weiteren Halogenangriff stabilisieren. Die gegenüber der Spaltung der Si–Si–Bindung bevorzugte Substitution des Hydridwasserstoffs in R5Si2H durch Halogene bietet einen weiteren Weg zur Gewinnung der Halogenide R5Si2X, deren vorsichtige Hydrolyse das unbeständige Silanol R5Si2OH liefert." @default.
- W2030664345 created "2016-06-24" @default.
- W2030664345 creator A5017767033 @default.
- W2030664345 date "1963-10-01" @default.
- W2030664345 modified "2023-10-16" @default.
- W2030664345 title "Spaltung von Methylpolysilanen mit Brom und Jod" @default.
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- W2030664345 doi "https://doi.org/10.1002/cber.19630961039" @default.
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