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- W2030667055 abstract "The microwave spectrum of 2-chloropyridine, C5H4NCl, has been studied in the frequency range from 26.5–40.0 GHz. The spectrum is characterized by strong parallel type transitions of a near-prolate asymmetric top. The assigned transitions have been used to evaluate the ground state rotational constants of the two chlorine isotopes. The rotational constants are (in MHz): A = 5872.52, B = 1637.83, C = 1280.48 for the 35Cl isotopic species and A = 5872.16, B = 1591.76, C = 1252.17 for the 37Cl isotopic species. The small inertial defect indicates the molecule is planar. In addition an excited vibrational state of C5H4N35Cl has been observed and analyzed. The chlorine quadrupolar coupling constants were determined for the ground state and are: χaa = −71.9 MHz for 35Cl and χaa = −54.9 MHz for 37Cl. By assuming the pyridine ring structure the CCl bond length is found to be 1.72 Å." @default.
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- W2030667055 date "1974-08-01" @default.
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- W2030667055 title "Microwave spectrum of 2-chloropyridine" @default.
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- W2030667055 doi "https://doi.org/10.1016/0022-2852(74)90115-5" @default.
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