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- W2030699959 abstract "A systematic study of the electrochemical oxidation of primary, secondary and tertiary aliphatic amides at platinum electrodes in aprotic solvents is reported. Results of product analyses, coulometry and cyclic voltammetry are presented. A mechanism is proposed which involves two different paths to stable products. One of these involves a one-electron. reaction with subsequent radical reaction. The other involves a two-electron process with subsequent reaction with base. Examples of both types are presented for secondary and tertiary amides. Only the one-electron process has been observed electrochemically with primary amides. Comparison of chemical and electrochemical oxidations is discussed." @default.
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- W2030699959 date "1967-01-01" @default.
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- W2030699959 title "Controlled-potential oxidation of aliphatic amides" @default.
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- W2030699959 doi "https://doi.org/10.1016/0022-0728(67)80108-6" @default.
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