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- W2030710588 abstract "The photoelectron and absorption spectra of NaF, NaCl, NaBr, and NaI were measured at room temperature and liquid-nitrogen temperature (LNT) to investigate the decay of the core exciton. The constant-initial-state (CIS) spectra with the initial state at the peak of the valence band of NaCl, NaBr, and NaI at LNT show two peaks around the excitation energy of the Na 2p core exciton, but the energy difference between these two peaks does not correspond to the spin-orbit splitting of the Na 2p core level. The higher-energy peak, which appears at the same photon energy and shows the same temperature dependence as those of the prominent exciton peak in the absorption spectrum, was interpreted as originating from the decay of the bulk-core exciton. On the other hand, the lower-energy peak, whose energy position does not coincide with that of the core-exciton peak in the absorption spectrum, was attributed to the decay of the surface-core exciton. In the case of NaF the CIS spectrum obtained at LNT shows the dip at the excitation energy of the Na 2p core exciton and the broad peak on the lower-energy side of the dip. This newly observed broad peak was attributed to another Na 2p core exciton distinct from the well-known Na 2p core exciton." @default.
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- W2030710588 date "1989-01-15" @default.
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- W2030710588 title "Temperature dependence of the nonradiative decay of the Na 2<i>p</i>core exciton in sodium halides" @default.
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- W2030710588 doi "https://doi.org/10.1103/physrevb.39.1307" @default.
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