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- W2030720312 abstract "Reaction of 2,3,5-tri-O-benzyl-d-ribofuranosyl bromide with mercuric cyanide afforded an anomeric mixture of cyanides (3) and 1,4-anhydro-2,3,5-tri-O-benzyl-d-erythro-pent-1-enitol (6). Reduction of 3 with lithium aluminum hydride gave a pair of epimeric amines (4 and 5), which were separated by chromatography and characterized by conversion into the known 2,5-anhydro-3,4,6-tri-O-benzyl-1-deoxy-1-ureido-d-allitol (7) and its epimer, 2,5-anhydro-3,4,6-tri-O-benzyl-1-deoxy-1-ureido-d-altritol (8). Compound 8 and its precursor were used for the synthesis of various “α-homonucleosides”." @default.
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- W2030720312 date "1973-12-01" @default.
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- W2030720312 title "The synthesis of the α-d-anomers of “homonucleosides”: derivatives of 2,5-anhydro-d-altritol" @default.
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- W2030720312 doi "https://doi.org/10.1016/s0008-6215(00)86189-3" @default.
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