Matches in SemOpenAlex for { <https://semopenalex.org/work/W2030755945> ?p ?o ?g. }
- W2030755945 endingPage "6845" @default.
- W2030755945 startingPage "6834" @default.
- W2030755945 abstract "A novel difunctional alkoxyamine initiator, DEPN2, was synthesized and utilized as an efficient initiator in nitroxide-mediated controlled radical polymerization of triblock copolymers. Complementary hydrogen-bonding triblock copolymers containing adenine (A) and thymine (T) nucleobase-functionalized outer blocks were synthesized. These thermoplastic elastomeric block copolymers contained short nucleobase-functionalized outer blocks (Mn ∼ 1K−4K) and n-butyl acrylate rubber blocks of variable length (Mn ∼ 14K−70K). Hydrogen-bonding interactions were observed for blends of the complementary nucleobase-functionalized block copolymers in terms of increased specific viscosity as well as higher scaling exponents for specific viscosity as a function of solution concentration. In the solid state, the blends exhibited evidence of a complementary A−T hard phase, which formed upon annealing, and dynamic mechanical analysis (DMA) revealed higher softening temperatures. Morphological development of the block copolymers was studied using SAXS and AFM, which revealed intermediate interdomain spacings and surface textures for the blends compared to the individual precursors. Hydrogen-bonding interactions enabled the compatibilization of complementary hydrogen-bonding guest molecules such as 9-octyladenine." @default.
- W2030755945 created "2016-06-24" @default.
- W2030755945 creator A5022667730 @default.
- W2030755945 creator A5025464166 @default.
- W2030755945 creator A5044785642 @default.
- W2030755945 creator A5065726426 @default.
- W2030755945 creator A5073572010 @default.
- W2030755945 creator A5080205965 @default.
- W2030755945 date "2007-08-28" @default.
- W2030755945 modified "2023-10-17" @default.
- W2030755945 title "Supramolecular Triblock Copolymers Containing Complementary Nucleobase Molecular Recognition" @default.
- W2030755945 cites W1969224882 @default.
- W2030755945 cites W1971097497 @default.
- W2030755945 cites W1971566080 @default.
- W2030755945 cites W1974865372 @default.
- W2030755945 cites W1982859026 @default.
- W2030755945 cites W1998482680 @default.
- W2030755945 cites W2004150278 @default.
- W2030755945 cites W2004286543 @default.
- W2030755945 cites W2006962710 @default.
- W2030755945 cites W2011987721 @default.
- W2030755945 cites W2014640356 @default.
- W2030755945 cites W2015461663 @default.
- W2030755945 cites W2016455930 @default.
- W2030755945 cites W2017119618 @default.
- W2030755945 cites W2019303915 @default.
- W2030755945 cites W2022219418 @default.
- W2030755945 cites W2023282027 @default.
- W2030755945 cites W2024495009 @default.
- W2030755945 cites W2024912231 @default.
- W2030755945 cites W2028039584 @default.
- W2030755945 cites W2034501059 @default.
- W2030755945 cites W2036510099 @default.
- W2030755945 cites W2037310827 @default.
- W2030755945 cites W2039985930 @default.
- W2030755945 cites W2040404466 @default.
- W2030755945 cites W2043856089 @default.
- W2030755945 cites W2050088472 @default.
- W2030755945 cites W2055425189 @default.
- W2030755945 cites W2058792727 @default.
- W2030755945 cites W2061032788 @default.
- W2030755945 cites W2061804721 @default.
- W2030755945 cites W2063466080 @default.
- W2030755945 cites W2068063111 @default.
- W2030755945 cites W2068949979 @default.
- W2030755945 cites W2071807757 @default.
- W2030755945 cites W2074151250 @default.
- W2030755945 cites W2082953598 @default.
- W2030755945 cites W2083365394 @default.
- W2030755945 cites W2088760600 @default.
- W2030755945 cites W2109196266 @default.
- W2030755945 cites W2144122182 @default.
- W2030755945 cites W2156462582 @default.
- W2030755945 cites W2159664510 @default.
- W2030755945 cites W2160602446 @default.
- W2030755945 cites W2161285191 @default.
- W2030755945 cites W2278539898 @default.
- W2030755945 cites W2952097536 @default.
- W2030755945 cites W4210963845 @default.
- W2030755945 cites W4245084629 @default.
- W2030755945 doi "https://doi.org/10.1021/ma070865y" @default.
- W2030755945 hasPublicationYear "2007" @default.
- W2030755945 type Work @default.
- W2030755945 sameAs 2030755945 @default.
- W2030755945 citedByCount "113" @default.
- W2030755945 countsByYear W20307559452012 @default.
- W2030755945 countsByYear W20307559452013 @default.
- W2030755945 countsByYear W20307559452014 @default.
- W2030755945 countsByYear W20307559452015 @default.
- W2030755945 countsByYear W20307559452016 @default.
- W2030755945 countsByYear W20307559452017 @default.
- W2030755945 countsByYear W20307559452018 @default.
- W2030755945 countsByYear W20307559452019 @default.
- W2030755945 countsByYear W20307559452020 @default.
- W2030755945 countsByYear W20307559452021 @default.
- W2030755945 countsByYear W20307559452022 @default.
- W2030755945 countsByYear W20307559452023 @default.
- W2030755945 crossrefType "journal-article" @default.
- W2030755945 hasAuthorship W2030755945A5022667730 @default.
- W2030755945 hasAuthorship W2030755945A5025464166 @default.
- W2030755945 hasAuthorship W2030755945A5044785642 @default.
- W2030755945 hasAuthorship W2030755945A5065726426 @default.
- W2030755945 hasAuthorship W2030755945A5073572010 @default.
- W2030755945 hasAuthorship W2030755945A5080205965 @default.
- W2030755945 hasConcept C112887158 @default.
- W2030755945 hasConcept C15920480 @default.
- W2030755945 hasConcept C159985019 @default.
- W2030755945 hasConcept C178790620 @default.
- W2030755945 hasConcept C185592680 @default.
- W2030755945 hasConcept C188027245 @default.
- W2030755945 hasConcept C192562407 @default.
- W2030755945 hasConcept C32909587 @default.
- W2030755945 hasConcept C38052585 @default.
- W2030755945 hasConcept C521977710 @default.
- W2030755945 hasConcept C552990157 @default.
- W2030755945 hasConcept C55493867 @default.
- W2030755945 hasConcept C61234307 @default.
- W2030755945 hasConcept C92328351 @default.