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- W2030763119 abstract "CeO2 cubes with {100} facets, octahedra with {111} facets, and wires with highly defective structures were utilized to probe the structure-dependent reactivity of acetaldehyde. Using temperature-programmed desorption (TPD), temperature-programmed surface reactions (TPSR), and in situ infrared spectroscopy, it was determined that acetaldehyde desorbs unreacted or undergoes reduction, coupling, or C–C bond scission reactions, depending on the surface structure of CeO2. Room-temperature FTIR indicates that acetaldehyde binds primarily as η1-acetaldehyde on the octahedra, in a variety of conformations on the cubes, including coupling products and acetate and enolate species, and primarily as coupling products on the wires. The percent consumption of acetaldehyde ranks in the following order: wires > cubes > octahedra. All the nanoshapes produce the coupling product crotonaldehyde; however, the selectivity to produce ethanol ranks in the following order: wires ≈ cubes ≫ octahedra. The selectivity and other dif..." @default.
- W2030763119 created "2016-06-24" @default.
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- W2030763119 date "2014-06-25" @default.
- W2030763119 modified "2023-10-04" @default.
- W2030763119 title "Adsorption and Reaction of Acetaldehyde on Shape-Controlled CeO<sub>2</sub> Nanocrystals: Elucidation of Structure–Function Relationships" @default.
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- W2030763119 doi "https://doi.org/10.1021/cs500611g" @default.
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