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• W2030771522 abstract "With a view to fabricating high glass transition temperature ( <i xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>Tg</i> ) graded-index plastic optical fiber (GI POF) by the coextrusion process, core material consisting of copolymer of 2,2,2-trichloroethyl methacrylate (TCEMA) and <i xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>N</i> -cyclohexyl maleimide (cHMI) (P(TCEMA-co-cHMI)), and diphenyl sulfide (DPS) as dopant was newly developed. Although homo polymer of TCEMA (PTCEMA) possesses high <i xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>Tg</i> and high transparency, it was found that PTCEMA began depolymerization at ca. 200 <sup xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>°</sup> C, which means that PTCEMA-based GI POF fabricated by the coextrusion process has low <i xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>Tg</i> due to depolymerized monomer. By copolymerizing TCEMA with cHMI (5 mol%), the rate of weight loss at constant temperature <i xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>T</i> = 230 <sup xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>°</sup> C was drastically decreased (15 wt%/hr). Moreover, the <i xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>Tg</i> linearly increased from 130 <sup xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>°</sup> C to 197 <sup xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>°</sup> C with increasing cHMI composition ratio from 0 to 62 wt%, respectively. Scattering loss of the copolymer was increased with the increase of cHMI composition ratio due to the refractive index difference between PTCEMA and PcHMI. It was found that the increment of the scattering loss was suppressed significantly when the copolymer includes DPS (120 dB/km decrease by adding 4 wt% DPS for the copolymer including 5 mol% cHMI). From these results, P(TCEMA-co-cHMI)-based core material was thought to be a promising candidate for high <i xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>Tg</i> GI POF." @default.
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• W2030771522 date "2012-01-01" @default.
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• W2030771522 title "Fabrication of High Glass Transition Temperature Graded-Index Plastic Optical Fiber: Part 1– Material Preparation and Characterizations" @default.
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• W2030771522 doi "https://doi.org/10.1109/jlt.2011.2180700" @default.
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