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- W2030793111 abstract "Starting from general quantum-mechanical expressions for the absorption and the emission coefficient of a vapour of radiating atoms in a perturbing gas, we derive a classical theory of foreign-gas broadening of spectral lines. Kirchhoff's law is used as a check on the consistency of the classical limit. Two distinct ways of taking the classical limit are found, leading to a quastatic and to a dynamical theory. We study the impact limit of the latter theory. The resulting classical expression for the line profile is more general than found in earlier theories, in that the Doppler effect is not neglected, no straight-line trajectories are assumed, and the effects of inelastic collisions are accounted for." @default.
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- W2030793111 date "1973-06-01" @default.
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- W2030793111 title "Classical limit of the quantum-mechanical theory of spectral-line broadening and Kirchhoff's law" @default.
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- W2030793111 doi "https://doi.org/10.1016/0031-8914(73)90329-7" @default.
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