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• W2030818187 abstract "A novel application of the cinchona alkaloid derivative (DHQD)2PHAL in the osmium-catalyzed asymmetric dihydroxylation of olefins is presented. In a triple catalytic system using H2O2 as the terminal oxidant, the alkaloid ligand has a dual function in providing stereocontrol in the addition step and, via its N-oxidized form, acting as reoxidant for the in situ generated osmium(VI). The formation of the N-oxide is catalyzed by a biomimetic flavin." @default.
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• W2030818187 date "2001-10-09" @default.
• W2030818187 modified "2023-10-02" @default.
• W2030818187 title "Osmium-Catalyzed Asymmetric Dihydroxylation of Olefins by H₂O₂; Dual Role of the Cinchona Alkaloid Ligand" @default.
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• W2030818187 doi "https://doi.org/10.1021/ol016450t" @default.
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