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- W2030851726 abstract "Abstract A new structural model for the FeMo-cofactor of nitrogenase, consisting of two Fe4S4 clusters bridged by an S2Mo2 unit, is proposed. Available chemical, spectroscopic, and EXAFS data are shown to be consistent with the proposed structure. In particular, EXAFS data are in agreement with m(Mo-Fe):n(Mo-S) of either 2:4 or 3:4; comparison with known Mo-Fe-S and Fe-S systems leads us to favor the former. Based on the proposed structural model, a possible mechanism of reduction of N2 is suggested." @default.
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- W2030851726 date "1979-06-01" @default.
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- W2030851726 title "A new cluster model for the FeMo-cofactor of nitrogenase" @default.
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- W2030851726 doi "https://doi.org/10.1016/0006-291x(79)91143-4" @default.
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