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- W2030853462 abstract "The apparent spin—orbit splitting of 4d energy levels in cadmium metal and cadmium dimethyl is discussed in terms of crystal-field and band-broadening models. The use of nuclear field gradients from Mössbauer and NQR measurements in distinguishing between these two models is evaluated by CNDO calculations on cadmium dimethyl and a cadmium atom cluster (Cd13). The calculations suggest that the use of nuclear field gradients cannot reliably distinguish between crystal-field and band-broadening mechanisms." @default.
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- W2030853462 date "1978-06-01" @default.
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- W2030853462 title "Crystal-field and band-broadening effects on the apparent 4d spin—orbit splitting in cadmium photoelectron spectra" @default.
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- W2030853462 doi "https://doi.org/10.1016/0009-2614(78)89002-2" @default.
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